Optical in-process height measurement system for process control of laser metal-wire deposition

We propose an in-process height measurement system for a weld bead and feedback control system for wire-feeding speed for high-quality laser deposition. Metal additive manufacturing, especially laser metal-wire deposition, is effective for complex shape fabrication and repair processing. However, we must control the gap between a weld bead and a feed wire in an optimal range for high-quality deposition. Conventionally, the Z-stage pitch for multi-layer deposition must be precisely adjusted by each deposition shape. In this paper, we design an in-process height measurement system that is integrated in a laser processing head, which measures the weld bead height by a line section method. We decreased the influence of the intense thermal radiation generated from a melt pool by inserting the band-pass filter of the line beam's wavelength in the imaging system and optimizing its line laser power. Consequently, our system can measure the weld bead height near the melt pool, which is 4 mm in front of it. Next we show that our proposed system can measure the weld bead height during wire-laser metal deposition with 50-μm accuracy by comparing its value to the true value. Finally, we achieved a cylinder shape deposition of 50-mm height, regardless of the Z-stage pitch and the cylinder diameter of the multi-layer deposition, by controlling the wire-feeding speed based on the measured weld bead height.     

中空夹层金属管混凝土构件侧向冲击试验研究

为提高海洋平台结构的抗冰能力，提出一种新型中空夹层金属管混凝土导管腿构件。通过理论分析、数值模拟和试验相结合，研究不同外钢管材料（Q345钢、奥氏体304级不锈钢和T6061铝合金）对中空夹层钢管混凝土构件的影响。通过单次冲击和连续冲击两种加载方式进行加载，并与钢质空心导管腿进行对比，试验结果发现：组合构件抗冲击性能优于空管构件，铝合金组合构件整体抗冲击能力较差，不锈钢单次冲击作用下极限承载能量高达18.83 kJ以上，小能量连续冲击作用下承载冲击次数最多，不锈钢组合构件抗冲击力学性能最好。结合有限元ABAQUS软件，对单次冲击构件建模并得出计算结果，与试验结果基本吻合。     

Highly stable and high power efficiency tandem organic light-emitting diodes with transition metal oxide-based charge generation layers

Tandem organic light-emitting diodes (OLEDs) have been studied to improve the long-term stability of OLEDs for 10 years. The key element in a tandem OLEDs is the charge generation layer (CGL), which provides electrons and holes to the adjacent sub-OLED units. Among different types of CGLs, n-doped electron transporting layer (ETL)/transition metal oxide (TMO)/hole transporting layer (HTL) has been intensively studied. Past studies indicate that this kind of CGL can achieve the desired efficiency enhancement, however, its long-term stability was reported not good and sometime even poor than a single OLED. This issue was not well addressed over the past 10 years. Here, for the first time, we found that this is caused by the unwanted diffusion of TMO into the underlying n-doped ETL layer and can be well resolved by introducing an additional diffusion suppressing layer (DSL) between them. Our finding will fully release the potential of TMO-based CGL in tandem OLEDs.     

High temperature Ir segregation in Ir–B ceramics: effect of oxygen presence on stability of IrB2 and other Ir–B phases

The formation of IrB₂, IrB_1.35, IrB_1.1 and IrB monoboride phases in the Ir–B ceramic nanopowder was confirmed during mechanochemical reaction between metallic Ir and elemental B powders. The Ir–B phases were analysed after 90 h of high energy ball milling and after annealing of the powder for 72 h at 1050°C in vacuo. The iridium monoboride (IrB) orthorhombic phase was synthesised experimentally for the first time and identified by powder X-ray diffraction. Additionally, the ReB₂ type IrB₂ hexagonal phase was also produced for the first time and identified by high resolution transmission electron microscope. Ir segregation along disordered domains of the boron lattice was found to occur during high temperature annealing. These nanodomains may have useful catalytic properties.     

空调复杂曲面钣金件的设计、分析及验证方法

本文讲述空调复杂空间曲面钣金件的设计思路及分析方法。主要从设计方法、模拟分析、零件测量比对等方面分析空间复杂曲面钣金件的设计思路,以满足结构使用要求、强度刚度以及经济要求。     

An effective approach to reinforced closed-cell Al-alloy foams with multiwalled carbon nanotubes

Exploring the reinforcing role of carbon nanotubes to obtain materials (polymers, metals, ceramics) with enhanced properties has been often attempted, but the success is strongly limited by the dispersing degree of carbon nanotubes. Here we report on an innovative colloidal approach to disperse the carbon nanotubes in the powders mixture of the precursor materials in order to profit from their reinforcing potential and obtain a new class of closed-cell metal foams. The feasibility of the proposed approach was demonstrated for aluminium foams reinforced with multi-walled carbon nanotubes. These nanocomposite metal foams synergistically combine the remarkable properties of both metal foams and carbon nanotubes. The results indicate that the tubular structure of carbon nanotubes is preserved throughout the entire the process. The carbon nanotubes are individually dispersed, stretched and randomly aligned in the aluminium-matrix of these closed-cell foams, thus potentiating their homogeneous 3D reinforcing role. Accordingly, the Vickers micro-hardness of the closed-cell foams was greatly enhanced.     

Template confined construction of Fe–NiCoP/NiCoP/NF heterostructures for highly efficient electrocatalytic oxygen evolution reaction

Rational design of oxygen evolution reaction (OER) electrocatalysts with advance nanostructures and composition superiority is an urgent need to promote electrocatalytic property. In this research, we fabricate Fe–NiCoP/NiCoP/NF electrocatalyst for OER via the interfacial scaffolding strategy with Prussian-blue-analogue (PBA) followed by low-temperature phosphating. The cube-on-sheet multimetallic-TMPs-based nanoarchitecture of Fe–NiCoP/NiCoP/NF exhibits outstanding OER performance, which only requires the overpotential of 201 mV to achieve a current density of 10 mA cm⁻² and possesses good durability up to 50 h in 1.0 M KOH solution. The superior OER property of Fe–NiCoP/NiCoP/NF is mainly characteristic to the rich composition that optimizes the electronic structure and the cube-on-sheet multimetallic-TMPs-based nanoarchitecture which can facilitate more effective active sites exposure and ultimately promote charge transfer at the same time. This research provides a new strategy for the construction of advanced nanoarrays structure and the improvement of the electrocatalytic performance of polymetallic phosphides, which offers its promising applications especially in energy storage and conversion technology.